pr int exi t permabond - division of national starch & chemical woodside road, eastleigh, hants., so50 4ex. united kingdom. helpline tel: +44 (0) 1703 619822 fax: +44 (0) 1703 652270 page 1 of 6 9 february, 1998 *** safety data sheet *** _________________________________________________________________________ 1. chemical product and company identification _________________________________________________________________________ product name....................... permabond A1046 permabond, division of national starch & chemical woodside road eastleigh hants. s050 4ex united kingdom emergency telephone: (44) 01703 629628 (business hours) _________________________________________________________________________ 2. composition/information on ingredients _________________________________________________________________________ chemical family.................... methacrylate ester component cas number concentration eec symbol/ ranges risk phrases _______________________ ____________ _______________ ________________ acrylic acid 79-10-7 1-<5% c r10, r34 hydroxypropyl 27813-02-1 >50% xi methacrylate r36/38 _________________________________________________________________________ 3. hazards identification _________________________________________________________________________ irritant. eye................................ moderate eye irritation. skin contact....................... frequent or prolonged contact may irritate the skin. inhalation......................... no hazard in normal industrial use. ingestion.......................... low order of toxicity. no hazard in normal industrial use.
permabond A1046 page 2 of 6 9 february, 1998 *** safety data sheet *** _________________________________________________________________________ 4. first-aid measures _________________________________________________________________________ eye................................ flush eyes with large amounts of water until irritation subsides. if irritation persists, get medical attention. skin contact....................... flush with large amounts of water; use soap if available. if irritation persists, get medical attention. inhalation......................... remove to fresh air. get medical attention if irritation persists. ingestion.......................... do not induce vomiting. if individual is conscious, give milk or water to dilute stomach contents. keep warm and quiet. get prompt medical attention. _________________________________________________________________________ 5. firefighting measures _________________________________________________________________________ autoflammability................... not applicable flash point........................ >100 c extinguishing media................ co2; dry chemical; foam; water fog special firefighting procedures.... fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes fire & explosion hazards........... combustion may release noxious or toxic vapours. see below. hazardous combustion products...... thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. upper explosion limit (%).......... not applicable lower explosion limit (%).......... not applicable _________________________________________________________________________ 6. accidental release measures _________________________________________________________________________ spill and leak procedures.......... take up with sand or other absorbent material and place in container for later disposal. this material should not be spilled, dumped, or flushed into sewers or public waterways. for safety and environmental precautions, please review entire safety data sheet for necessary information.
permabond A1046 page 3 of 6 9 february, 1998 *** safety data sheet *** _________________________________________________________________________ 7. handling and storage _________________________________________________________________________ storage temperature................ ambient. special sensitivity................ keep away from heat. handling/storage................... store in cool, dry place. ventilation requirements........... general; normal room ventilation should be adequate. if vapours or dust are a nuisance near the work area, local mechanical ventilation should be provided. sensitive to static electricity?... no sensitivity to mechanical impact... no _________________________________________________________________________ 8. exposure controls/personal protection _________________________________________________________________________ component exposure limits _________________________________ _________________________________ acrylic acid 2 ppm (skin) (acgih-twa) hydroxypropyl methacrylate 20 ppm (manufacturer) ventilation requirements........... general; normal room ventilation should be adequate. if vapours or dust are a nuisance near the work area, local mechanical ventilation should be provided. eye protection requirements........ avoid contact with eyes. wear chemical goggles if there is likelihood of contact with eyes. glove requirements................. the use of chemically resistant gloves is recommended. clothing requirements.............. overalls or lab coat should be worn. respiratory requirements........... none required under normal handling conditions. _________________________________________________________________________ 9. physical and chemical properties _________________________________________________________________________ pure substance or preparation...... preparation physical form...................... liquid appearance/odour................... green; acrylic odour odour threshold.................... not available. ph as is........................... not applicable
permabond A1046 page 4 of 6 9 february, 1998 *** safety data sheet *** _________________________________________________________________________ 9. physical and chemical properties ( continued ) _________________________________________________________________________ boiling point...................... not applicable melting/freezing point............. not applicable solubility in water................ insoluble partition coefficient (n-octanol/water)................ not applicable relative density................... 1.070 evaporation rate................... not applicable vapour pressure (mmhg)............. not applicable vapour density (air=1)............. not applicable viscosity.......................... 9000 mpa.s volatiles.......................... none. volatile organic compounds......... <5 g/l autoflammability................... not applicable flash point........................ >100 c oxidizing properties............... not applicable _________________________________________________________________________ 10. stability and reactivity _________________________________________________________________________ stability.......................... stable materials to avoid................. acids; bases; peroxides hazardous decomposition products... thermal decomposition could produce carbon monoxide, carbon dioxide, and unidentified organic compounds. hazardous polymerization conditions....................... an oxygen-free atmosphere may cause hazardous polymerization. _________________________________________________________________________ 11. toxicological information _________________________________________________________________________ chronic (long term) effects of exposure _______________________________________ route of entry..................... inhalation; skin contact; eye contact effects of chronic exposure........ although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. use of good industrial hygiene practices is recommended. target organs...................... not applicable special health effects............. none known.
permabond A1046 page 5 of 6 9 february, 1998 *** safety data sheet *** _________________________________________________________________________ 12. ecological information _________________________________________________________________________ potential effect on environment.... unknown. mobility........................... unknown. persistence and degradability...... unknown potential to bioaccumulate......... unknown ecotoxicity........................ unknown. aquatic toxicity................... none established. _________________________________________________________________________ 13. disposal considerations _________________________________________________________________________ waste disposal methods............. waste disposal should be in accordance with existing community,national and local regulations. empty container warnings........... empty containers may contain product residue; follow sds and label warnings even after they have been emptied. _________________________________________________________________________ 14. transport information (see also section 9) _________________________________________________________________________ adr/rid............................ not applicable cefic tremcard number.............. not applicable hazchem code....................... not applicable kemmler code....................... not applicable imdg classification................ not applicable iata classification................ not applicable marine pollutant................... no u.n. number (s.i.n.)............... not applicable u.n. class, packing group.......... not applicable _________________________________________________________________________ 15. regulatory information _________________________________________________________________________ eec hazard classification.......... irritant. risk phrases....................... r36/38 - irritating to eyes and skin. safety phrases..................... s24 - avoid contact with skin. s26 - in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. directives 88/379/eec and 91/155/eec have been considered when compiling
permabond A1046 page 6 of 6 9 february, 1998 *** safety data sheet *** _________________________________________________________________________ 15. regulatory information ( continued ) _________________________________________________________________________ this sds; the information is provided for health and safety assessment by an industrial user. reference should be made to any relevent local or national health, safety, and environmental legislation. this information does not constitute indication of suitability for specific uses. _________________________________________________________________________ 16. other information _________________________________________________________________________ msds date.......................... 6 february, 1998 changes since previous issue....... section 2; section 9; section 15; section 16 for regulatory information, contact: simon ward product assurance supervisor adhesives - europe national starch & chemical ltd. galvin road slough, berkshire sl1 4df united kingdom telephone: (+44) 01753 533494 fax: (+44) 01753 577704
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