product safety data sheet according to ec directive 91/155/eec and subsequent amendments version: 1.0 revision date: 28.06.2000 dow corning(r) 732 adhesive sealant black 1 of 7 1. identification of the substance and of the company trade name : dow corning(r) 732 adhesive sealant black company : dow corning europe rue gnral de gaulle 62 b-1310 la hulpe belgium service : dow corning central europe tel: +49 6112371 fax: +49 611237609 : dow corning northern europe tel: +44 1676528000 fax: +44 1676528001 : dow corning southern europe tel: +33 472841360 fax: +33 472841379 emergency phone number : dow corning (barry u.k. 24h) dow corning (wiesbaden 24h) tel: +44 1446732350 tel: +49 61122158 2. composition / information on ingredients chemical characterization: silicone elastomer hazardous ingredients: name cas-no. conc. (% w/w) classification methyltriacetoxysilane 4253-34-3 2.0 c r34 ethyltriacetoxysilane 17689-77-9 2.0 c r34
product safety data sheet according to ec directive 91/155/eec and subsequent amendments version: 1.0 revision date: 28.06.2000 dow corning(r) 732 adhesive sealant black 2 of 7 3. hazards identification the principal hazards of the product as supplied are: not hazardous according to council directive 88/379/eec and its subsequent amendments. 4. first aid measures on contact with eyes : flush with water. on skin contact : wipe off and wash with soap and water. if inhaled : remove to fresh air. on ingestion : no first aid should be needed. 5. fire fighting measures suitable extinguishing media : carbon dioxide, foam, dry powder or fine water spray. water can be used to cool fire exposed containers. unsuitable extinguishing media : none known. hazards during fire fighting : none known. special protective equipment/procedures : a self-contained respirator and protective clothing should be worn. keep containers cool with water spray until well after the fire is out. determine the need to evacuate or isolate the area according to your local emergency plan. hazardous combustion products : silica. carbon oxides and traces of incompletely burned carbon compounds. formaldehyde. 6. accidental release measures personal precautions : wear proper protective equipment.
product safety data sheet according to ec directive 91/155/eec and subsequent amendments version: 1.0 revision date: 28.06.2000 dow corning(r) 732 adhesive sealant black 3 of 7 precautions to protect the environment : do not allow large quantities to enter drains or surface waters. methods for cleaning up : scrape up and place in a container fitted with a lid. the spilled product produces an extremely slippery surface. 7. handling and storage advice on safe handling : general ventilation is recommended. avoid skin and eye contact. do not breathe vapour. advice on storage : do not store with oxidizing agents. keep container closed and store away from water or moisture. unsuitable packaging materials : none known. 8. exposure controls / personal protection exposure controls : refer to section 7 exposure controls for hazardous components name cas-no. exposure limits silica, amorphous 7631-86-9 6 mg/m3 twa inhalable dust 2.4 mg/m3 twa respirable dust methyltriacetoxysilane 4253-34-3 10 ppm twa, 15ppm stel as acetic acid. name cas-no. exposure limits methyltriacetoxysilane 4253-34-3 10 ppm twa, 15ppm stel as acetic acid. ethyltriacetoxysilane 17689-77-9 10 ppm twa, 15ppm stel as acetic acid. personal protection equipment
product safety data sheet according to ec directive 91/155/eec and subsequent amendments version: 1.0 revision date: 28.06.2000 dow corning(r) 732 adhesive sealant black 4 of 7 respiratory protection : suitable respiratory protection should be worn if the product is used in large quantities, confined spaces or in other circumstances where the oel may be approached or exceeded. hand protection : chemical protective gloves should be worn. eye protection : safety glasses should be worn. skin protection : protective equipment is not normally necessary. hygiene measures : exercise good industrial hygiene practice. wash after handling, especially before eating, drinking or smoking. additional information : none known. 9. physical and chemical properties appearance form: paste colour: black odour: acetic acid other data explosive properties :no specific gravity :1.04 oxidizing properties :no the above information is not intended for use in preparing product specifications. contact dow corning before writing specifica tions.
product safety data sheet according to ec directive 91/155/eec and subsequent amendments version: 1.0 revision date: 28.06.2000 dow corning(r) 732 adhesive sealant black 5 of 7 10. stability and reactivity stability : stable under normal usage conditions. conditions to avoid : none established. materials to avoid : can react with strong oxidising agents. cures in the presence of water or moisture, releasing a small amount of acetic acid. hazardous decomposition products : see section 11. 11. toxicological information on contact with eyes 3 : vapours released during curing may cause eye irritation. on skin contact 3 : can irritate on prolonged or repeated contact. if inhaled 3 : the vapour is irritating to the mouth, nose and throat. on ingestion 3 : small amounts transferred to the mouth by fingers during use should not injure. swallowing large amounts may cause digestive discomfort. other health hazard information : product may emit formaldehyde vapours at temperatures above 150 c in the presence of air. formaldehyde vapour is harmful by inhalation and irritating to eyes and respiratory system at breathing concentration less than one part per million (1 ppm). 1 based on product test data. 2 based on assessments from related products. 3 this information is based either on test data, extrapolation from tests on similar materials, review of component data, or a combination of these sources. 12. ecological information environmental fate and distribution solid material, insoluble in water. no adverse effects are predicted. ecotoxicity effects no adverse effects on aquatic organisms are predicted. bioaccumulation : no bioaccumulation potential. fate and effects in waste water treatment plants
product safety data sheet according to ec directive 91/155/eec and subsequent amendments version: 1.0 revision date: 28.06.2000 dow corning(r) 732 adhesive sealant black 6 of 7 no adverse effects on bacteria are predicted. 13. disposal considerations product disposal : dispose of in accordance with local regulations. packaging disposal : dispose of in accordance with local regulations. 14. transport information road / rail (adr/rid) not subject to adr/rid. sea transport (imdg) not subject to imdg code. air transport (icao) not subject to icao regulations. 15. regulatory information labelling according to eec directive r-phrases : not hazardous according to council directive 88/379/eec and its subsequent amendments. s-phrases : s24 avoid contact with skin. s51 use only in well-ventilated areas. national legislation / regulations ozone depleting chemicals : no ozone depleting chemicals are present or used in manufacture. status einecs : all ingredients listed or exempt. tsca : all chemical substances in this material are included on or exempted from listing on the tsca inventory of chemical substances.
product safety data sheet according to ec directive 91/155/eec and subsequent amendments version: 1.0 revision date: 28.06.2000 dow corning(r) 732 adhesive sealant black 7 of 7 16. other information this product safety data sheet was prepared in compliance with commission directive 93/112/ec, 67/548/eec and 88/379/eec as well as their relevant amendements, on the approximation of laws, regulations and administrative provisions relative to the classification, packaging and labelling of dangerous substances and preparations. it is the responsibility of persons in receipt of this product safety data sheet to ensure that the information contained herein is properly read and understood by all people who may use, handle, dispose or in any way come in contact with the product. if the recipient subsequently produces a formulation containing the dow corning product, it is the recipient's sole responsibility to ensure the transfer of all relevant information from the dow corning product safety data sheet to their own product safety data sheet in compliance with commission directive 88/379/eec. all information and instructions provided in this safety data sheet (sds) are based on the current state of scientific and technical knowledge at the date indicated on the present sds. dow corning shall not be held responsible for any defect in the product covered by this sds , should the existence of such defect not be detectable considering the current state of scientific and technical knowledge. as stated above, this safety data sheet has been prepared in compliance with applicable european law. if you purchase this material outside europe, where compliance laws may differ, you should receive from your local dow corning supplier a sds applicable to the country in which the product is sold and intended to be used. please note that the appearance and content of the sds may vary - even for the same product - between different countries, reflecting the different compliance requirements. should you have any question, please refer to your local dow corning supplier.
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