rocol as anti-scuffing spray 10025 2.00 gb en 22.12.1997 msds.en hazardous components in product for ec safety data sheet safety data sheet ref. no. 10025 1. product and company identification trade name rocol as anti-scuffing spray manufacturer/supplier rocol lubricants address rocol house, swillington, leeds, ls26 8bs, england phone number +44 (0) 113 2322700 fax number +44 (0) 113 2322760 emergency phone number +44 (0) 113 2322600 2. composition/information on the components component name cas no. concentration r phrases classification acetone 000067-64-1 10.00 - 30.00 r11 f xylene, mixture of isomers 1330-20-7 0.00 -3.00 r10, r20/21, r38 xn, xi, f hydrocarbon aerosol propellant (<0.1% 1,3 butadiene) 68476-85-7 50.00 - 70.00 r12 f+ r10 flammable. r11 highly flammable. r12 extremely flammable. r20/21 harmful by inhalation and in contact with skin. r38 irritating to skin. f f - highly flammable f+ f+ - extremely flammable xi xi - irritant xn xn - harmful f flammable
3. hazard identification main hazards extremely flammable. health effects - eyes liquid may cause slight transient irritation. health effects - skin repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. health effects - ingestion swallowing may have the following effects:- nausea. drowsiness. health effects - inhalation exposure to vapour at high concentrations may have the following effects:- drowsiness. 4. first aid measures first aid - eyes wash out eye with plenty of water.obtain medical attention if soreness or redness persists. first aid - skin wash skin with soap and water. apply a reconditioning skin cream. first aid - ingestion do not induce vomiting. obtain medical attention. first aid - inhalation remove from exposure. 5. fire fighting measures extinguishing media keep containers and surroundings cool with water spray. use foam, dry chemical or carbon dioxide. unsuitable extinguishing media do not use water jet. special hazards of product containers may explode in heat of fire. this product may give rise to hazardous fumes in a fire. protective equipment for fire - fighting wear self contained breathing apparatus. 6. accidental release measures personal precautions eliminate all sources of ignition.ventilate the area. material can create slippery conditions underfoot. environmental precautions try to prevent the material from entering drains or water courses.advise authorities if spillage has entered water course or sewer or has contaminated soil or vegetation. spillages allow to evaporate if it is safe to do so or contain and absorb using earth, sand or other inert material. transfer into suitable containers for recovery or disposal. 7. handling and storage handling use in well ventilated area. storage storage temperature should be kept below 50 c. storage area should be: out of direct sunlight. 8. exposure controls/personal protection occupational exposure standards acetone uk eh40: oes 750ppm 8h twa. uk eh40: oes 1500ppm 15min twa. xylene, mixture of isomers uk eh40: oes 100ppm 8h twa. uk eh40: oes 150ppm 15min twa. hydrocarbon aerosol propellant (<0.1% 1,3 butadiene) occupational exposure standards for significant components are: uk eh40: oes 1750mg/m3 8h twa. uk eh40: oes 2180mg/m3 15min twa. (lpg) uk eh40: oes 1450mg/m3 8h twa. uk eh40: oes 1810mg/m3 15min twa. (butane) the minimal atmospheric oxygen concentration should be 18% by volume under normal atmospheric pressure.
engineering control measures exposure to this material may be controlled in a number of ways.the measures appropriate for a particular worksite depend on how the material is used and on the potential for exposure. use of the basic principles of industrial hygiene will enable this material to be used safely. respiratory protection respiratory protection if there is a risk of exposure to high vapour concentrations. hand protection use a good quality barrier cream. eye protection chemical goggles if there is a risk of eye contact. body protection normal work wear. protection during application during application, adequate ventilation must be provided. 9. physical and chemical properties physical state liquid. colour blue. - black. odour characteristic. boiling range/point ( c) boils above 50. flash point (pmcc) ( c) <0 (based on major component) explosion limits (%) not determined. solubility in water (kg/m3) insoluble. vapour pressure (mm.hg./20 c) 185 (based on major component) density (kg/m3) 0.8. (measured as kg/litre) auto - flammability ( o c) above 200. viscosity (cst) mobile liquid at ambient temperatures. vapour density (air = 1) heavier than air. evaporation rate 7.7 (referenced as n - butyl acetate = 1) (based on major component) 10. stability and reactivity stability stable under normal conditions. conditions to avoid temperatures in excess of 50 c. exposure to direct sunlight. materials to avoid strong oxidising agents. hazardous decomposition products combustion will generate: smoke, possibly thick and choking, resulting in zero visibility. 11. toxicological information acute toxicity low order of acute toxicity. 12. ecological information mobility the product is volatile/gaseous and will partition to the air phase. if released to water the product will float. persistence/degradability the product is expected to be resistant to biodegradation. bio - accumulation product is not expected to bioaccumulate.
13. disposal container disposal plastic caps and empty aerosols may be recycled via appropriate routes. empty aerosols may be disposed of by authorised landfill. do not incinerate closed containers. 14. transport information un number 1950 un proper shipping name aerosols un class 2.1 uk proper shipping name aerosols uk classification 2.1 uk transport category 2 adr/rid - class 2 adr/rid - item no. 5 f imdg - proper shipping name aerosols imdg - class 2.1 imdg - page no. 2102 imdg - ems number 2 - 13 imdg - mfag table number 620 iata - proper shipping name aerosols, 30 iata - class 2.1 tremcard no. tec(r) 20g26 15. regulatory information labelling information extremely flammable labelling information r phrases extremely flammable. s phrases keep away from sources of ignition - no smoking. do not breathe spray. use only in well ventilated areas. keep out of reach of children. 16. other information product use for industrial use only. lubricant. msds first issued 19 august 1997 msds data revised 22 december 1997 revisions highlighted transport information footnote completely revised 8/97
17. national legislation ec legislation ec directive 91/155/eec defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. ec directive 88/379/eec relating to the classification, packaging and labelling of dangerous preparations. ec directive 94/1/ec adapting some technicalities of council directive 75/324/eec on the approximation of the laws of member states relating to aerosol dispensers. uk guidance publications eh40, occupational exposure limits, hse.revised annually. to the best of our knowledge, the information contained herein is accurate. although certain hazards may be described we cannot predict that these are the only hazards, or combination of hazards, that may exist in a workplace. this msds, therefore, forms a component only of a risk assessment carried out by, or on behalf of, the user.
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